Nomenclature Bayhydrol®

K 2010
Customer

New decorative and convenient solutions for glass coatings


Decorative alternatives to through-colored glass

Polyurethane, glass coatingWhen it comes to giving glass a colored appearance, today there are alternatives to coloring molten glass. The variety of colors and surface textures can be increased significantly. If glass is coated rather than produced by the traditional method of using colored glass melt, only one - transparent – glass melt instead of several different needs to be operated and stocked. Therefore any special coloring can be obtained in small batches without the use of any possibly toxic heavy metal salts. In addition, polyurethane-based glass coatings satisfy even very demanding requirements on the properties in daily use.
Another advantage of this method is the easier recycling. There is no need for sorting differently colored glass. During the remelting process any organic material is simply combusted leaving a clear transparent product.

Polyurethane coatings provide additional functional properties
Polyurethane, glass coatingThe coloring of glass with polyurethane-based coatings opens the opportunity to add special properties enhancing its practical value. The polyurethane coating can perform functional tasks like the protection from mechanical and chemical stress. It increases scratch resistance, adds shatter protection and makes it more dishwasher proof.

Functional polyurethane-based coatings can increase the resistance to internal stresses (burst protection). With a polyurethane coating the internal stress resistance of lightweight glass bottles can be increased to the standard of regular bottles.

New effects
Other than the characteristics mentioned above like abrasion- and chemical resistance, the polyurethane dispersions show particular rheological characteristics. They make it possible to formulate effect coatings like metallic, pearl or other special effects. In addition the formulation of softfeel-coatings with an exceptional surface haptic is possible if highly flexible systems are used.


Applications and their requirements

Stoving systems
Requirements
Starting Formulations
Returnable bottles
  • Caustic resistance
  • Abrasion resistance
RR 6898
Decorative glass ware
  • Soap resistance
  • Brilliance
  • Effects
RR 6899
Perfume bottles
  • Effects
RR 6899
Non-returnable bottles
  • Alcohol resistance
  • Effects
RR 6897
Decorative flatglass
  • Effects
RR 6899
Low temperature systems
Air dry systemsExample: Interior window coatings
  • Fast drying
  • Brilliance
RR 6900

The product range for glass coating
Bayer MaterialScience offers amino resin-crosslinkable polyester and polyarcrylate dispersions and also a one- and two-component polyurethane based product range of raw materials for glass coating. Compared to other alternatives Bayhydrol® polyurethane dispersions offer some distinct benefits:
    • best combination of durability and flexibility
    • high resistance against chemical agents, e.g. caustic solutions and acids
    • very good adhesion on glass surfaces
    • excellent scratch and abrasion resistance
Due to the increasing need to reduce VOC emissions, water based one-component baking systems are more and more replacing the conventional two-component polyurethane systems. Waterbased glass coatings can be formulated with products like these:

Waterbased dispersion:
Type
Solids in %
% OH
on solids
Viscosity
mPas
at 23°C
Characteristics
Bayhydrol®
U XP 2239
Polyurethane dispersion
35
4.6
4000
In combination with Bayhydur® BL 5335 for coatings with high scratch resistance and resistance against solvents and caustic soda solution (an NMP-free version is being worked on)
Bayhydrol®
E XP 2777
Polyester dispersion
64
2.0
11500
In combination with melamine resins and/or blocked isocyanates (see presentation)

Polyisocyanate crosslinker for waterbased dispersions:
Type
Solids in %
% NCO
on solids
Viscosity
mPas
at 23°C
Characteristics
Bayhydur®
BL 5335
blocked polyisocyanate
35
7.1 (blocked)
20*
In combination with Bayhydur® VP LS 2239 for coatings with high scratch resistance and resistance against solvents and caustic soda solution
Bayhydur®
BL XP 2706
blocked polyisocyanate
41
8.8 (blocked)
> 300
For glass coatings with increased hardness and better yellowing resistance (see presentation)

More products, starting formulations and technical service are available on request.

Have a look at this detailed presentations:

"Bayhytherm®, Bayhydur® BL, Bayhydrol® Dispersions for one-component stoving applications"

Product presentation on Bayhydrol® E XP 2777

Product presentation on Bayhydur® BL XP 2706

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