Nomenclature Bayhydrol®

K 2010
Customer

Polyurethane top coats for plastics – excellent surfaces with high-gloss or matt-finish

Top coats protect plastic substrates from outside influences such as chemicals or light, but they are also important for coloring and design. Under normal circumstances top coats are pigmented unlike clear coats. Depending on the individual requirements they can be applied in a single layer or as a multi-layer coating (Primer, base coat, top coat).

Due to their good curing properties at low temperatures polyurethane systems have become the standard technology for top coats. Surface characteristics like high-gloss or a matt finish can be adjusted according to individual needs by the use of special fillers, binders or matting agents.

Particularly interesting effects can be obtained with soft-feel coatings. They add a comfortable, luxurious and warm touch to plastic substrates of automotive interior or housings of mobile phones.

A selection of polyurethane raw materials for waterborne top coats

Waterbased dispersions:
Type
Solids
in %
% OH
on solids
Viscosity
mPas
at 23°C
Characteristics
Bayhydrol®
U 241
Polyester polyurethane
dispersion
41
2.5
1000
Good pigment wetting, high shearing stability
Bayhydrol®
A 145
Polyacrylate dispersion
45
3.3
990
In combination with polyisocyanates for high-gloss two-component polyurethane hydro coats with good film hardness and weather stability
Bayhydrol®
A 2427
Polyacrylate dispersion
42
2.0
80
For fast drying two-component primers and topcoats and for one-component coatings
Bayhydrol®
A 2542
Polyacrylate dispersion
50
3.8
2250
In combination with polyisocyanates for high-gloss two-component polyurethane hydro coats with good film hardness and weather stability
Bayhydrol®
A XP 2645
Polyacrylate dispersion
43
4.5
2000
For waterbased two-component hydro coats with good chemical resistance and weather resistance
Bayhydrol®
A 2058
Polyacrylate dispersion
42
4.8
1000
In combination with e.g. Bayhydur® 3100 for high-gloss solvent resistant top coats
Bayhydrol®
AH XP 2754
high molecular polyacrylate dispersion
40
-
20
For wood coatings with excellent chemical and stain resistance - good wood wetting
Bayhydrol®
A 2290
Polyester
polyacrylate
dispersion
45
3.6
< 200
In combination with Bayhydur® 3100 for high-gloss, solvent and tar resistant top coats, overcoatable, good mechanical properties
Bayhydrol ®
A 2139/2
Polyester polyacrylate copolymer
48
3.8
1850
In combination with e.g. Bayhydur® 3100 for high-gloss solvent resistant top coats
Bayhydrol®
U XP 2750
Polyurethane
dispersion
43
3.6
1000
For clearcoats and topcoats with very good weather resistance


Isocyanate crosslinkers for waterbased dispersions:
Type
Solids
in %
% NCO
on solids
Viscosity
mPas
at 23°C
Characteristics
Bayhydur®
3100
HDI
polyisocyanate
100
17.4
2800
Hardener for waterborne two component polyurethane systems, additive for waterborne high-quality coating systems
Bayhydur®
XP 2655
HDI Polyisocyanate
100
21.2
3500
Hardener for waterborne two-component polyurethane systems (easy mixing) and additive for high-quality waterborne coating systems
Bayhydur®
XP 2487/1
HDI Polyisocyanat
100
20.6
5400
Cross-linker for waterborne two component polyurethane systems, developed for safe processing. Films with high chemical resistance
Bayhydur®
304
HDI Polyisocyanat
100
18.2
4000
Hardener for waterborne two component polyurethane systems and additive for waterborne high-quality coating systems
Bayhydur®
305
HDI Polyisocyanate
100
16.2
6500
Hardener for waterborne two-component polyurethane systems (easy mixing) and additive for high-quality waterborne coating systems
Bayhydur®
XP 2759
IPDI-
Poyisocyanate
70
11.0
6500
Hydrophilic crosslinker, in combination with HDI-based grades to enhance drying properties


Some starting formulations


RR PCO 0027e-TC

Two-component polyurethane top coat
(Bayhydrol® VP LS 2139/2 / Bayhydur® 3100)




RR PCO 0069e-TC

Two-component polyurethane top coat
(Bayhydrol® VP LS 2290 / Bayhydur® 304 or Bayhydur® XP 2655)




RR 4540 ABCe

Two-component polyurethane clear and top coat
(Bayhydrol® A145 / Bayhydur® 304)


A Selection of polyurethane raw materials for solventborne top coats

Type
Solids in %
% NCO or OH on solids
Viscosity
mPas at 23°C
Characteristics
Desmophen®
670 BA
Polyester
polyol
80
4.4 OH
3000
In combination with e.g. Desmodur® N 75 MPA
or Desmodur® N 3390 BA/SN for excellent films with very good weather resistance, which are elastic at low temperatures
Desmophen®
1300
Polyester
polyol
100
4.3 OH
3600
Reaction partner for polyisocyanates, for air curing 2component polyurethane coatings
Desmophen®
C 1100
Polycarbonate polyester polyol
100
3.3 OH
3200
For the elastification of binders for hart coatings, e.g. like Desmophen® XP 2488
Desmophenr®
XP 2488
Polyester
polyol
100
16.0 OH
14500
For highly resistant, but hart coatings
Desmodur® N 3390 BA/SN
HDI
trimer
90
21.8 NCO
550
High gloss, good chemical and weather resistance, lightfast, good mechanical resistance
Desmodur®
N 75 MPA
HDI
biuret
75
22.0 NCO
250
Lightfast, good chemical and weather resistance, high gloss, outstanding mechanical properties

An example for a suitable starting formulation


RR 4842

Elastic two-component polyurethane topcoat
(Desmophen® 670 / Desmodur® N 75)


Have a look at this in-depth information:

Brochure: “Easy emulsification plus improved chemical resistance - Hydrophilic polyisocyanate with high functionality improve waterborne Two-component PUR coatings”

"The New Frontier: Waterborne UV Coatings for Plastics" (This presentation received the Paul Dufour Award at the RadTech 2007)

Presentation for the ECS 2007: New PUR dispersions for waterborne one-component coatings

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"Download entire brochure on dispersions"